Rev.Adv.Mater.Sci.(RAMS)
No 2, Vol. 6, 2004, pages 94 - 119

STRUCTURAL PROPERTIES OF DIAMOND NANOWIRES:
THEORETICAL PREDICTIONS AND EXPERIMENTAL PROGRESS

Amanda S. Barnard

Center for Nanoscale Materials, Argonne National Laboratory, 9700 South Cass Ave,
Argonne, IL, 60439, USA

Abstract

Although the nanoscience and nanotechnology surrounding sp2 bonded carbon nanotubes has continued to flourish over recent years the development of the sp3 analogue, diamond nanowires, has been slow. Diamond-based materials have unique structural properties such as high elastic modulus and strength-to-weight ratio, making them ideal candidates for structural applications at the nanoscale. While few experimentalists have succeeded in synthesizing such materials, a number of researchers have used various theoretical models to compare the structure and stability of diamond nanowires as a function of morphology and size. In this review a summary of these theoretical predictions is given along with the progress made by experimentalists in the synthesis of quasi-one dimensional diamond nanostructures.

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