Rev.Adv.Mater.Sci. (RAMS)
No 3, Vol. 15, 2007, pages 192-197

ELECTRONIC PROPERTIES OF GRAPHITE-LIKE ION TRACKS IN INSULATING TETRAHEDRAL
AMORPHOUS CARBON

Anne-Katrin Nix, Daniel Schwen, Carsten Ronning, Johann Krauser, Christina Trautmann and Hans Hofsäss

Abstract

We investigated the formation of quasi one-dimensional conducting filaments in tetrahedral amorphous carbon (ta-C) films created by swift heavy ion irradiation. Various ta-C films with thicknesses of about 100 nm were grown using mass-separated ion beam deposition on highly conducting Si and Ni substrates. After deposition, the films were irradiated with 1GeV 238U ions at fluences between 109 and 1011 ions/cm2. Due to their high electronic energy loss of about 40 keV/nm, the swift heavy ions graphitize the predominantly (70%) sp3-bound tertahedral amorphous carbon film (ta-C) along their trajectories, yielding conducting nanowires embedded in an insulating matrix. Using atomic force microscopy (AFM) with conducting cantilevers and an applied bias voltage the presence of conducting tracks was confirmed and their conductivities were determined to be several orders of magnitude higher than that of the host matrix. Temperature-dependent electrical measurements were performed on the irradiated samples at 300K - 15K with fields of up to 5V/μ.

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