Rev.Adv.Mater.Sci.(RAMS)
No 5, Vol. 5, 2003, pages 459-463

STUDIES OF SURFACE PROPERTIES AND FRACTAL DIMENSIONS OF CARBON NANOTUBES USING COMPLEX METHODS

P. Staszczuk1, M. Matyjewicz1, E. Kowalska2, J. Radomska2, P. Byszewski3, M. Kozłowski2

1 Department of Physicochemistry of Solid Surface, Chemistry Faculty,
Maria Curie-Sklodowska University, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland
2 Industrial Institute of Electronics, Długa Str. 44/50, 00-241 Warsaw, Poland
3 Institute of Physics, Polish Academy of Sciences, Lotnikow Av. 32/46, 02-668 Warsaw, Poland

Abstract

Physicochemical properties of carbon nanotube surfaces by means of the special thermogravimetry (Q-TG), sorptometry and atomic force microscopy (AFM) methods were investigated. A numerical and analytical procedure for the evaluation of total heterogeneous properties (desorption energy distribution and pore-size distribution functions) on the basis of liquid thermodesorption from the sample surfaces under the quasi-equilibrium conditions and sorptometry techniques are presented. The desorption energy distribution was derived from the mass loss Q-TG and the differential mass loss Q-DTG curves of thermodesorption of pre-adsorbed polar and apolar liquid films. For the first time, the evaluation of the fractal dimensions of nanotubes using the sorptometry, Q-TG and AFM data are presented.

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